Trichloramine

   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
Properties
General
Name Nitrogen trichloride
Chemical formula NCl3
Appearance Yellow oily liquid
CAS number 10025-85-1
Physical
Formula weight 120.36 amu
Melting point 233 K (-40 °C)
Boiling point 344 K (71 °C)
Odor Pungent, chemical odor
Thermochemistry
ΔfH0gas  
ΔfH0liquid  
S0gas, 1 bar  
Safety
Ingestion Hazardous due to decomposition to chlorine and ammonia
Inhalation Irritant, hazardous due to decomposition to chlorine and ammonia, may cause asthma attacks in sensitive individuals
Skin Unknown
Eyes Irritant, may cause burns in sufficient quantity
More info OSHA
SI units were used where possible. Unless otherwise stated, standard conditions were used.

Disclaimer and references

The chemical compound nitrogen trichloride (trichloramine) is a chloramine, with chemical formula NCl3. A yellow, oily, pungent-smelling liquid, it is often found as a byproduct of chemical reactions between many nitrogen-containing compounds and chlorine. Nitrogen trichloride was trademarked as Agene and used to artificially bleach and age flour. When purified, it is highly unstable. It decomposes in the presence of light or water, usually in less than 24 hours. Purified nitrogen trichloride explodes on contact with organic compounds or catalytic surfaces, by impacts and shock waves, or by self-heating during its decomposition. Bubbling chlorine gas through a solution of ammonium nitrate (and other ammonium salts) yields yellow droplets of nitrogen trichloride. Nitrogen trichloride may be formed in small amounts when public water supplies are disinfected with monochloramine, a combination of chlorine and ammonia. In 2003, Belgian researchers reported a possible link between trichloramine and rising numbers of childhood asthma cases. See also:

External links

* OSHA - Nitrogen trichloride

 

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