Half-reaction

A half reaction is either the oxidation or reduction reaction component of a redox reaction. A half reaction is obtained by considering the change in oxidation states of individual substances involved in the redox reaction. Consider the reaction below: (1) Cl2 + 2Fe2+ -> 2Cl- + 2Fe3+ The two elements involved, iron and chlorine, each change oxidation state - iron from 2+ to 3+, chlorine from 0 to 1-. There are then effectively two half-reactions occurring. These changes can be represented in formulas by inserting appropriate electrons in to each half-reaction:
  (3) Fe2+ -> Fe3+ + e-   (4) Cl2 + 2e- -> 2Cl-    
In the same way given two half-reactions it is possible, with knowledge of appropriate electrode potentials, to arrive at the full (original) reaction. :See also: Electrode potential

 

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