Dimethylmercury

   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
Properties
center
General
Name Dimethylmercury
Chemical formula CH3HgCH3
Appearance Colorless liquid
Physical
Formula weight 230.659 amu
Melting point 230 K (-43 °C)
Boiling point 360-370 K (87-97 °C)
Density ? kg/m3
Solubility ?
Thermochemistry
ΔfH0gas ? kJ/mol
ΔfH0liquid 55-60 kJ/mol
ΔfH0solid 162.2 kJ/mol
S0gas, 1 bar ? J/mol·K
S0liquid, 1 bar ? J/mol·K
S0solid ? J/mol·K
Safety
Ingestion Fatal
Inhalation Fatal
Skin Fatal
Eyes Fatal
SI units were used where possible. Unless otherwise stated, standard conditions were used.
     

Dimethylmercury (CH3HgCH3) is a flammable, colorless liquid, and is described as having a slightly sweet smell. It is an extremely dangerous chemical. Absorption of doses as low as 0.1 mL are fatal. Dimethylmercury can seep through rubbers and plastics. Therefore, most laboratory gloves do not provide adequate protection from this chemical.

Use

Dimethylmercury is most often used in toxicology experiments as a fixed point of reference due to its extreme toxicity. It has also been used to calibrate NMR instruments for detection of mercury.

Well known incidents involving dimethylmercury

In 1997, Dr. Karen Wetterhahn, an experienced chemist working at Dartmouth College, died after she was exposed to dimethylmercury. After her death, the Karen Wetterhahn Memorial Award was created in her honor. Its purpose is to "recognize an outstanding graduate student or post-doctoral researcher who studies metals and best demonstrates the qualities of scientific excellence exhibited by Dr. Wetterhahn". http://www-apps.niehs.nih.gov/sbrp/products/products11.cfm

See also

External links

 

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