Carbenoid

In chemistry a carbenoid is a reactive intermediate that shares reaction characteristics with a carbene. In the Simmons-Smith reaction the carbenoid intermediate is a zinc / iodine complex that takes the form of I-CH2-Zn-I This complex reacts with an alkene to a cyclopropane just as a carbene would do.

references

  • Organic Chemistry john McMurry Brooks /Cole Publishing Company 1988 ISBN 0-534-079-68-7

 

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