Beckmann Rearrangement

In chemistry, the Beckmann rearrangement is the rearrangement of a ketoxime to the corresponding amide in concentrated sulfuric acid, phosphorus pentachloride or a few other catalysts. The oxime is formed by the reaction of a ketone with hydroxylamine. reactionsceme This example reaction starting with cyclohexanone to the caprolactam is the most important application of the Beckmann rearrangement. The caprolactam is hydrolysed and then polymerized to Nylon.

 

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