Mulliken Scale
The
Mulliken scale
(also called
Mulliken-Jaffe scale
) is a scale for the
electronegativity
of
chemical elements
. It was developed by
Robert S. Mulliken
in
1934
. It is based on the
Mulliken electronegativity
,
c
M
, which is related to the
electron affinity
EA
v
(the tendency of an atom to become negatively charged) and the
ionization potential
IE
v
(the tendency of an atom to become positively charged):
c
M
= (IE
v
+ EA
v
)/2 Some example values:
Element
Al
Ar
As
B
Be
Br
C
Ca
Cl
F
Ga
Ge
H
I
In
K
Kr
Li
c
M
1.37
3.36
2.26
1.83
1.99
3.24
2.67
1.30
3.54
4.42
1.34
1.95
3.06
2.88
1.30
1.03
2.98
1.28
Element
Mg
N
Na
Ne
O
P
Rb
S
Sb
Se
Si
Sn
Sr
Te
Xe
c
M
1.63
3.08
1.21
4.60
3.21
2.39
0.99
2.65
2.06
2.51
2.03
1.83
1.21
2.34
2.59
See also :
Pauling scale
--
Allred-Rochow scale
--
Electronegativity
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